Dept. of Chemistry and Materials Science Seminar
- Friday, September 7, 2018 at 3:10pm
- Chemistry & Biochemistry Building, Byker - view map
Dr. Sean Roberts from the Department of Chemistry at the University of Texas -Austin will present "Manipulating Energy and Spin for Photon Up- and Down-conversion."
The negligible spin-orbit coupling in many organic molecules creates opportunities to alter the energy of excited electrons by manipulating their spin. In particular, molecules with a large exchange splitting have garnered interest due to their potential to undergo singlet fission (SF), a process where a molecule in a high-energy spin-singlet state shares its energy with a neighbor, placing both in a low-energy spin-triplet state. When incorporated into photovoltaic and photocatalytic systems, SF can offset losses from carrier thermalization, which account for ~50% of the energy dissipated by these technologies. Likewise, compounds that undergo SF’s inverse, triplet fusion (TF), can be paired with infrared absorbers to create structures that upconvert infrared into visible light. In this presentation, I will review our group’s efforts to create organic:inorganic structures that use SF and TF for improved light harvesting and photon upconversion.
- Department of Chemistry and Biochemistry